The closest to this is if you know the item code of the item, you can create short-cut for that item (regardless of whether its in your backpack or not). If you want it to actually "use" the item, you then have to make sure it is in backpack.
In an unreleased version of Item Compendium, I'm using this to get a temporary icon for each item. (ideally I'd like the real icon resource id vs having to create the shortcut).
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