im afraid not :/ Lotro is very restricted when it comes to modding.
There is values to change buff icon size however in skindefinition.xml - I think. However they are not active at the time but that might change when book 8 goes live as Frosty has mentioned much of the code will be enabled then.
And of course there is the promise of dev's UI revamp (they have kinda promised that over a year already) and there has been talk about seperating buffs from vitals alltogether.
But that's just guessing..
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